Update DCI number after event has begun
There is no convenient way that I am aware of.
As with all these problems though, you can save the tournament, edit the save-file with the text editor of your choice (I prefer Notepad++), save the changes and import the event, overwriting the old one. Works like a charm on any event, really. Just make sure to replace all instances of the changed DCI# or live in fear of copious amounts of error messages. ;)